June 6, 2014
MORDANTS

Mordants are used alongside natural dyes to make colours lightfast and washfast, as well as enhance or dull colour results. Experimenting with mordants and after baths is a great way to increase the spectrum of colours in your palette. 

Mordanting can be done before (premordanting),during dyeing (simultaneous mordanting), or after dyeing (after bath). 

Here are a list of common mordants:

Alum – Aluminum Potassium Sulphate - Brightening Mordant
USE AT 15% WOF

A white powder or crystal that accentuates yellow tones. Pickling alum or
Ammonium Potassium Sulphate is a non-poisonous substitute. Alum is
commonly used in conjunction with Cream of Tartar.

Tin – Stannous Chloride - Brightening Mordant
USE AT 1% WOF

A white crystal that enhances gold, red and orange. Because it ‘hardens’ the wool, it should always be given soapy rinses.

Copper – Cupric Sulphate – Dulling Mordant
USE AT 2% WOF

A blue crystal, also called vitriol, that enhances greens and browns.

Iron – Ferrous Sulphate - Dulling Mordant
USE AT 2% WOF
A green crystal, also called green vitriol or copperas that accentuates greys or tans. Performs well as an after-bath over alum/copper. Rust water can be used as an alternative to iron.  You can make rust water by soaking rusty objects (such as nails or an old bike chain) in 1 part vinegar, 1 part water. 

Dye additives are often used in combination with mordants, or as part of after baths:

Cream of Tartar – Potassium Bitartrate. USE AT 5% WOF WITH ALUM- A white powder that adds brightness and buffers the harshness of mordants.

Vinegar – Acetic Acid: Is used to soften hard water, to brighten colours, and, to neutralize an alkaline bath. LOWER PH LEVEL TO 4 MINIIMUM

Salt – Sodium Chloride: Any form of cooking salt can be used to soften colours and to slow the rate of colour absorption.

Thiourea Dioxide (Spectralite): A reducing agent used in Indigo dyeing and an excellent substitution for sodium hydrosulfite in color stripping and discharge. It is safer to use, has a greater strength, and does not lose its strength over time. It can be used for stripping cellulose fibre or bleaching wool or silk.

TNA Soap: A clear liquid soap for washing when using dyes, which is non-ionic and pH neutral. This soap also helps prevent staining of white or light areas during the wash-off procedure. (other brands: Synthrapol, Texascour)

Sodium Carbonate (Soda Ash): Used to develop and set a dyebath, increase pH, changes colour of some nature dyes towards reds/purples, neutralize an acidic dyebath RAISE PH TO 10 MAXIMUM. Common baking soda (sodium bicarbonate) is very similar but much weaker

MORDANT PROCESS FLOW CHART

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-Notes and flow chart provided by Laurie Wassink (Instructor), MAAD 2B38, Fibre: Dyeing, OCAD University